The settings you will need are the same as you use on your phone, namely the IMAP settings for your company. This includes using your email address and Mailbox password, which can be set separately and differently than your MRSware Desktop password. To get your specific company settings, please contact MRSware Support or ask your company's MRSware Administrator.
Likewise, to sync your Calendar to Windows 10 Mail, make sure your Administrator as added the Sync settings for your account, and can provide you with the login they created for your when doing so.
Some people like videos, some like text with images. There are lots of options to suit everyones' needs. Select your desired format from a lengthy list of options.